Sorry to be dense, but do you mean design them thick and then thin/polish them, or leave the final margin thick?
We've had no problem polishing ours. jus like tyler said, take a used Carbide and run over the surface - you don't have to design thicker, you're taking barely anything off. Once you've run it over with a carbide, you should be able to polish and high shine very well.
We did full contour SLM years ago for a doctor and it looked amazing. Also, due to no oxide layer, it was super easy to get it thiner where we needed it.
Another though, I've been meaning to try this, but can't we try and electropolish? i wonder if that would work.